Joanne Bertonazzi, Lynn M. Bradley, and David A. Hunt. The College of New Jersey, Ewing, NJ
In an attempt to develop a novel route to dibenzoazepine derivatives, functionalized aryllithium reagents were added to isatoic anhydrides at low temperatures. Instead of isolating the desired tricycles, 2-amino benzophenone derivatives were isolated. A rationale for this observation will be discussed. Preliminary results from the reduction of these functionalized benzophenones indicate that this method may permit a novel entry to 1-phenyl-1,3-dihydroisobenzofuran derivatives.

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