Wednesday, 16 May 2007
3rd Floor Hall (Pfahler Hall)
83

Neighboring fluorine effects on amide conformations of N-acetyl-5-mono-fluoro or 5,6-difluoro substituted methano prolines

Deepa Rapolu, Ram Edupuganti, Fang Yu, Charles Debrosse, Philip Sonnet, and Grant Krow. Temple University, Philadelphia, PA

The influence of fluorine substituents on N-hybridization, dipole moments and Kt/c for amide conformations of methano prolines have been investigated using NMR and calculations. Synthetic route to fluoro methanoprolines have been devised.


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