A novel catalytic asymmetric method for the synthesis of (Z)-disubstituted allylic alcohols will be presented. Our one-pot procedure entails hydroboration of chloro alkynes and addition of a hydride source (t-BuLi), which results in formation of a (Z)-vinylborane. Boron to zinc transmetalation of the vinyl group with ZnEt₂ and addition of a chiral ligand and substrate aldehyde results in formation of racemic (Z)-allylic alcohols. Unfortunately, the LiCl (generated on addition of t-BuLi ) is a much faster catalyst than the asymmetric catalyst. We have found, however, that addition of TEEDA to inhibit the background reaction promoted by LiCl allows direct generation of enantioenriched (Z)-allylic alcohols for the first time.