A μ6-oxo centered nickel(II)hexanuclear complex, ([Ni6(EtSNO)6(OMe)2O](ClO4)2) is formed when a solution of nickel(II) perchlorate is added to 3-(ethylsulfanyl)-3-ethylbutan-2-one oxime (EtSNOH) in the presence of triethylamine. Structural and magnetic properties will be discussed in detail. Magnetic measurements reveal that anti-ferromagnetic interactions dominate at high temperature and give rise to unusual bulk magnetic properties at low temperature.
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