Tuesday, May 20, 2008 - 11:35 AM
Medical Arts Building, Rm M-134 (Queensborough Community College)
382

Use of Vanadium Hydrides to Effect Radical Cyclizations

Jack Norton, Mary E. Pulling, and Deborah M. Smith. Columbia University, New York, NY

The vanadium hydrides HV(CO)4(P–P) (P–P = dppm, dppe, dppp, dppb) transfer H• rapidly to the methylene carbon of appropriate 1,6-dienes, and thereby bring about radical cyclizations.


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