Monday, May 19, 2008 - 3:20 PM
Medical Arts Building, Rm M-143 (Queensborough Community College)
246

Solvation and Solvation Dynamics in Room-Temperature Ionic Liquids

Sergei Arzhantsev, Hui Jin, and Mark Maroncelli. The Pennsylvania State University, University Park, PA

Room temperature ionic liquids (ILs) are currently being studied as new solvent media for a variety of purposes. Our interest lies in understanding solvation energetics and solvation dynamics in this distinctive environment. Steady-state and time-resolved fluorescence spectroscopy are used to measure solvation energies and dynamics in several series of imidazolium, pyrrolidinium and ammonium ionic liquids. The combination of femtosecond Kerr-gated emission spectroscopy and picosecond time correlated single photon counting are used to measure the full solvation response in ionic liquids. The observed solvation dynamics is highly non-exponential and extends over four decades in time. This non-exponential temporal response probably originates from dynamical heterogeneity similar to that found in supercooled liquids.